Volume 4, Issue 4 (12-2018)                   jhehp 2018, 4(4): 175-179 | Back to browse issues page


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Tazerodi A J, Akbari H, Mostafapour F. Adsorption of Catechol from Aqueous Solutions Using Graphene Oxide. jhehp 2018; 4 (4) :175-179
URL: http://jhehp.zums.ac.ir/article-1-190-en.html
1- Department of Environmental Health, Student Research Committee, Zahedan University of Medical Sciences, Zahedan, Iran.
2- Department of Environmental Health, Health Promotion Research Center, Zahedan University of Medical Sciences, Zahedan, Iran.
Abstract:   (11815 Views)
Background: Catechol is considered as apriority pollutant, since it is harmful to organisms even at low concentrations, and has been classified as hazardous pollutants. The aim of this study was to investigate catechol adsorption by graphene oxide of aqueous solution.
Methods: This study was an experimental-laboratory research. The batch adsorption system was utilized to evaluate the Catechol removal efficiency under different amount of effective parameters including contact time, adsorbent dosages and Catechol concentration. The experimental data were analyzed by the Langmuir, Freundlich, Temkin isotherm models.
Results: R2 value of Langmuir isotherm model is higher than other models and maximum monolayer coverage (qmax) was calculated to be 79.08 mg/g and the separation factor indicating a favorable sorption experiment is 0.242. Also from Freundlich isotherm model, the intensities of adsorption (n) that indicated favorable sorption is 3.324. The maximum removal efficacy (94.7%) was at concentration 100 mg/L, pH 7, adsorbent dosage 1200 mg/L and contact time 75 min.
Conclusion: According to the results, the adsorption process using graphene oxide was effective in the removal of catechol. Therefore, the use of this cost-effective agent is recommended as a proper alternative for the removal of catechol from aqueous solutions.
Full-Text [PDF 575 kb]   (8336 Downloads)    
Type of Study: Original Article | Subject: Environmental Health, Sciences, and Engineering
Received: 2018/10/23 | Accepted: 2018/12/4 | Published: 2018/12/21

References
1. Khalfa A, Mellouk S, Marouf-Khelifa K, Khelifa A. Removal of Catechol from Water by Modified Dolomite: Performance, Spectroscopy, and Mechanism. Water Sci Technol. 2018; 77(7): 1920-30. [Crossref]
2. Cohen SH, Belinky PA, Hadar Y, Carlos G. Dosoretz D. Characterization of Catechol Derivative Removal by Lignin Peroxidase in Aqueous Mixture. Bioresour Technol. 2009; 100: 2247-53. [Crossref]
3. Schweigert N, Zehnder AJB, Eggen RL. Chemical Properties of Catechols and Their Molecular Modes of Toxic Action in Cells, from Microorganisms to Mammals. Environ. Microbiol. 2001; 3: 81-91. [Crossref]
4. Suresh S, Srivastava VC, Mishra IM. Adsorption of Catechol, Resorcinol, Hydroquinone, and Their Derivatives: A Review. Int J Energy Environ Eng. 2012; 32(3): 1-19. [Crossref]
5. Balarak D, Joghataei A. Biosorption of Phenol Using Dried Rice Husk Biomass: Kinetic and Equilibrium Studies. Der Pharma Chemica. 2016; 8(6): 96-103.
6. Kumar A, Kumar S, Kumar S. Adsorption of Resorcinol and Catechol on Activated Carbon: Equilibrium and Kinetics. Carbon. 2003; 41: 3015-25. [Crossref]
7. Namasivayam C, Sumithra S. Adsorptive Removal of Catechol on Waste Fe(III)/Cr(III) Hydroxide:  Equilibrium and Kinetics Study. Ind Eng Chem Res. 2004; 43(23): 7581-87. [Crossref]
8. Shakir K, Ghoneimy HF, Elkafrawy AF, Beheir SG, Refaat M. Removal of Catechol from Aqueous Solutions by Adsorption onto Organophilic-Bentonite. J Hazard Mater. 2008; 150: 765-73. [Crossref]
9. Balarak D , Bazrafshan E, Mahdavi Y. Biosorption of Pyrocatechol Using Dried Lemna minor: Kinetic and Equilibrium Studies. Zanko J Med Sci. 2015; 16 (50): 13-26.
10. Zhou Z, Ping L, Jun L. Application of Natural Biosorbent and Modified Peat for Bisphenol a Removal from Aqueous Solutions. Carbohydr Polym. 2012; 88(2): 502-8. [Crossref]
11. Senturk H, Ozdesa D, Gundogdua A, Durana C, Oylak M. Removal of Phenol from Aqueous Solutions by Adsorption onto Organo-Modified Tirebolu Bentonite: Equilibrium, Kinetic and Thermodynamic Study. Hazard Mater. 2009; 172: 353-62. [Crossref]
12. Mandal A, Ojha K, De AK. Removal of Catechol from Aqueous Solution by Advanced Photo-oxidation Process. Chem Eng J . 2004; 102(2): 203-8. [Crossref]
13. Sadler A, Subrahmanyam VV, Ross D. Oxidation of Catechol by Horseradish Peroxidase and Human Leukocyte Peroxidase: Reactions of O-benzoquinone and Obenzosemiquinone. Toxicol Appl Pharmacol. 1988; 93(1): 62-71. [Crossref]
14. Gholizadeh A, Kermani M, Gholami M, Farzadkia M. Comparative Investigation of 2-Chlorophenol and 4-Chrorophenol Removal Using Granulated Activated Carbon and Rice Husk Ash. Tolooe Behdasht. 2013; 11(3): 66-78
15. Diyanati RA, Yousefi Z, Cherati JY. The Ability of Azolla and Lemna minor Biomass for Adsorption of Phenolic Compounds from Aqueous Solutions. J Mazandaran Univ Med Sci. 2013; 23(106): 21-8.
16. Kumar Nadavala S, Swayampakula K, Boddu VM, Abburia K. Biosorption of Phenol and Ochlorophenol from Aqueous Solutions on to Chitosan Calcium Alginate Blended Beads. J Hazard Mater. 2009; 162: 482-9. [Crossref]
17. Williams G, Seger B, Kamat PV. TiO2–Graphene Nanocomposites. UV-Assisted Photocatalytic Reduction of Graphene Oxide. ACS Nano. 2008; 2: 1487-91. [Crossref]
18. Akhavan O, Abdolahad M, Esfandiar A, Mohatashamifar M. Photodegradation of Graphene Oxide Sheets by TiO2 Nanoparticles after a Photocatalytic Reduction. J Phys Chem C. 2010; 114: 12955-9. [Crossref]
19. Yang ST, Chen S, Chang Y, Cao A, Liu Y. Removal of Methylene Blue from Aqueous Solution by Graphene Oxide. J Colloid Interface Sci. 2011; 359: 24-9. [Crossref]
20. Zazoulli MA, Balarak D. The Ability of Azolla and Lemna minor Biomass to Adsorption Pcresol from Aqueous Solutions: Isotherms and Kinetics. J Health Field. 2014; 2(1): 35-45.
21. Sui Q, Huang J, Liu Y, Chang X, Ji G, Deng S, et al. Rapid Removal of Bisphenol A on Highly Ordered Mesoporous Carbon. J Environ Sci. 2008; 23(2): 172- 82. [Crossref]
22. Qadeer R. A Study of the Adsorption of Phenol by Activated Carbon from Aqueous Solutions. Turk J Chem. 2002; 26: 357-61.
23. Balarak D, Mahdavi Y, Kord Mostafapour F, Joghataei A. Batch Removal of Acid Blue 292 dye by Biosorption onto Lemna minor: Equilibrium and Kinetic Studies. J Hum Environ Health Promot. 2016; 2(1): 9-19. [Crossref]
24. Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM. Adsorptive Removal of Phenol by Bagasse Fly Ash and Activated Carbon: Equilibrium, Kinetics and Thermodynamics. Colloids Surf A Physicochem Eng Asp. 2006; 272: 89-104. [Crossref]
25. Subramanyam B, Das A. Study of the Adsorption of Phenol by Two Soils Based on Kinetic and Isotherm Modeling Analyses. Desalination. 2009; 249(3): 914-21. [Crossref]
26. Moussavi SP, Mohammadian Fazli M. Acid Violet 17 Dye Decolorization by Multi-Walled Carbon Nanotubes from Aqueous Solution. J Hum Environ Health Promot. 2016; 1(2): 110-7. [Crossref]
27. Banat FA, Al-Bashir B, Al-Asheh S, Hayajneh O. Adsorption of Phenol by Bentonite. Environ Pollut. 2000; 107(3): 391-8. [Crossref]
28. Balarak D, Mahdavi Y, Jogatayi A. Removal of Phenolic Compounds Using Canola Stalks Waste as a new low Cost adsorbent Int J Innov Res Sci Eng Technol. 2015; 2(8): 735-44.
29. Baker HM, Ghanem R. Evaluation of Treated Natural Zeolite for the Removal of Ochlorophenol from Aqueous Solution. Desalination. 2009; 249: 1265–72. [Crossref]
30. Balarak D, Dashtizadeh M, Abasizade H, Baniasadi M. Isotherm and Kinetic Evaluation of Acid Blue 80 Dye Adsorption on Surfactant-Modified Bentonite. J Hum Environ Health Promot. 2018; 4 (2): 75-80. [Crossref]

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