Volume 4, Issue 2 (6-2018)                   jhehp 2018, 4(2): 87-93 | Back to browse issues page


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Bagheri M, Nasiri M, Talaiekhozani A, Abedi I. Equilibrium Isotherms of Formaldehyde Elimination from the Aqueous Solutions Containing Natural Adsorbents of Rice Bran and the Resulting Ashes. jhehp 2018; 4 (2) :87-93
URL: http://jhehp.zums.ac.ir/article-1-158-en.html
1- Department of Chemical Engineering, Jami Institute of Technology, Isfahan, Iran.
2- Department of Chemistry, Malekashtar University of Technology, Isfahan, Iran.
3- Department of Civil Engineering, Jami Institute of Technology, Isfahan, Iran.
Abstract:   (9432 Views)
Background: In this pioneering work, the comparisons conducted on the elimination efficiency of formaldehyde by rice bran and the resulting ashes utilized in the adsorption process.
Methods: In this study the optimal hydraulic retention time, temperature, pH value and adsorbents dosage for the elimination of formaldehyde using three adsorbents including rice bran, ashes of rice bran produced in 300°C (Carbon-300) and in 500°C (Carbon-500) were determined. The method of one factor at the time was used to optimize the above mentioned factors.
Results: The best adsorption conditions for 1000 mg/L of formaldehyde and 1 g of adsorbent in acidic environment (pH = 4) is reported at 80°C (with elimination percentage of 70%w/w for rice bran, 83%w/w for carbon-300 and 90%w/w for carbon-500). Also it was revealed that the adsorption of formaldehyde by rice bran adsorbent and Carbon-300 is a function of Langmuir adsorption isotherm while the resulting carbon in 500°C is a function of Freundlich adsorption isotherm.
Conclusion: In all experiments, the rice bran ashes showed much greater capacity for formaldehyde removal than one for rice bran. Rice bran is an ideal option in terms availability and the resulting waste could be eliminated through incineration.
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Type of Study: Original Article | Subject: Environmental Health, Sciences, and Engineering
Received: 2018/04/9 | Accepted: 2018/05/26 | Published: 2018/06/20

References
1. Talaiekhozani A, Fulazzaky MA, Ponraj M, Abd Majid ZM. Formaldehyde from Production to Application. In the 3th Conference of Application of Chemistry in Novel Technologies. 2013: 1-16.
2. Salthammer T, Mentese S, Marutzky R. Formaldehyde in the Indoor Environment. Chem Rev. 2010; 110(4): 2536-72. [Crossref]
3. Kajitvichyanukul P, Lu MC, Jamroensan A. Formaldehyde Degradation in the Presence of Methanol by Photo-Fenton Process. J Environ Manage. 2008; 86(3): 545-53. [Crossref]
4. Parisheva Z, Nusheva L, Licheva P. Comparison of the Effect of Ozone, Ozone-Hydrogen Peroxide System and Catalytic Ozonation on Formaldehyde Removal from Aqueous Model Solutions. Environ Prot Eng. 2004; 30(3): 5-13.
5. Hasanbeiki O, Miranzadeh MB, Mostafaei GR, Rabbani D, Akbari H. Feasibility of Formaldehyde Removal from Aqueous Solutions by Advanced Oxidation Process (UV/H2O2). Feyz J. 2014; 17(6): 568-74.
6. De Leon CP, Pletcher D. Removal of Formaldehyde from Aqueous Solutions via Oxygen Reduction Using a Reticulated Vitreous Carbon Cathode Cell. J Appl Electrochem. 1995; 25(4): 307-14. [Crossref]
7. Liang WJ, Li J, Li JX, Zhu T, Jin YQ. Formaldehyde Removal from Gas Streams by Means of NaNO2 Dielectric Barrier Discharge Plasma. J Hazard Mater. 2010; 175(1): 1090-5. [Crossref]
8. Hidalgo A, Lopategi A, Prieto M, Serra J, Llama M. Formaldehyde Removal in Synthetic and Industrial Wastewater by Rhodococcus erythropolis UPV-1. Appl Microbiol Biotechnol. 2002; 58(2): 260-4. [Crossref]
9. Ghanbarnejad P, Goli A, Bayat B, Barzkar H, Talaiekhozani A, Bagheri M, et al. Evaluation of Formaldehyde Adsorption by Human Hair and Sheep Wool in Industrial Wastewater with High Concentration. J Environ Treat Tech. 2014; 2(1): 12-7.
10. Talaiekhozani A, Talaei MR, Yazdan M, Mir SM. Investigation of Formaldehyde Removal from Synthetic Contaminated air by Using Human Hair. Environ Health Eng Manage J. 2016; 3(4): 191-6. [Crossref]
11. Talaiekhozani M, Bagheri M, Ghotbinasabet S, Talaie MR. The Experimental Study of Formaldehyde Adsorption Process by Human Hair. Health Syst Res. 2011; 6: 735-43.
12. Agarwal M, Dave M, Upadhayaya S. Adsorption of Formaldehyde on Treated Activated Carbon and Activated Alumina. Curr World Environ. 2011; 6(1): 53-9. [Crossref]
13. Wang Z, Zhong M, Chen L. Coal-Based Granular Activated Carbon Loaded with MnO2 as an Efficient Adsorbent for Removing Formaldehyde from Aqueous Solution. Desalin Water Treat. 2016; 57(28): 13225-35. [Crossref]
14. Paliulis D. Removal of Formaldehyde from Synthetic Wastewater Using Natural and Modified Zeolites. Pol J Environ Stud. 2016; 25(1): 251-7 [Crossref]
15. Matsuo Y, Nishino Y, Fukutsuka T, Sugie Y. Removal of Formaldehyde from Gas Phase by Silylated Graphite Oxide Containing Amino Groups. Carbon. 2008; 46(8): 1162-3. [Crossref]
16. Song Y, Qiao W, Yoon SH, Mochida I, Guo O, Liu L. Removal of Formaldehyde at Low Concentration Using Various Activated Carbon Fibers. J Appl Polym Sci. 2007; 106(4): 2151-7. [Crossref]
17. Ma C, Li X, Zhu T. Removal of Low-Concentration Formaldehyde in air by Adsorption on Activated Carbon Modified by Hexamethylene Diamine. Carbon. 2011; 49(8): 2873-5. [Crossref]
18. Tanada, S, Kawasaki N, Nakamura T, Araki M, Isomura M. Removal of Formaldehyde by Activated Carbons Containing Amino Groups. J Colloid Interface Sci. 1999; 214(1):106-8. [Crossref]
19. Rong H, Liu Z, Wu O, Pan D, Zheng J. Formaldehyde Removal by Rayon-Based Activated Carbon Fibers Modified by P-aminobenzoic Acid. Cellulose. 2010; 17(1): 205-14. [Crossref]
20. Rezaee A, Rangkooy H, Jonidi-Jafari A, Khavanin A. Surface Modification of Bone Char for Removal of Formaldehyde from Air. Appl Surf Sci. 2013; 286: 235-9. [Crossref]
21. Demirbas A. Heavy Metal Adsorption onto Agro-Based Waste Materials: A review. J Hazard Mater. 2008; 157(2-3): 220-9. [Crossref]
22. Yang HS, Kim DJ, Kim HJ. Rice Straw–Wood Particle Composite for Sound Absorbing Wooden Construction Materials. Bioresour Technol. 2003; 86(2): 117-21. [Crossref]
23. Bansal M, Garg U, Singh D, Gar VK. Removal of Cr (VI) from Aqueous Solutions Using Pre-Consumer Processing Agricultural Waste: A Case Study of Rice Husk. J Hazard Mater. 2009; 162(1): 312-20. [Crossref]
24. Federation WE, Association APH. Standard Methods for the Examination of Water and Wastewater. APHA: Washington, DC, USA; 2005.
25. Tchobanoglous G, Burton FL, Stensel HD. Wastewater Engineering. Management. 1991; 7: 1-4.
26. Shin S, Song J. Modeling and Simulations of the Removal of Formaldehyde Using Silver Nano-Particles Attached to Granular Activated Carbon. J Hazard Mater. 2011; 194: 385-92. [Crossref]

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